{"created":"2023-07-27T04:46:33.782880+00:00","id":47102,"links":{},"metadata":{"_buckets":{"deposit":"b81267ad-55bd-49f5-9e68-f31bc627a19a"},"_deposit":{"created_by":3,"id":"47102","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"47102"},"status":"published"},"_oai":{"id":"oai:tohoku.repo.nii.ac.jp:00047102","sets":["76:267"]},"author_link":["110931","110930","110929","110928","110932"],"item_4_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1996-03-22","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2","bibliographicPageEnd":"218","bibliographicPageStart":"215","bibliographicVolumeNumber":"41","bibliographic_titles":[{"bibliographic_title":"Science reports of the Research Institutes, Tohoku University. Ser. A, Physics, chemistry and metallurgy"}]}]},"item_4_date_62":{"attribute_name":"登録日","attribute_value_mlt":[{"subitem_date_issued_datetime":"2008-05-02","subitem_date_issued_type":"Created"}]},"item_4_date_63":{"attribute_name":"公開日（投稿完了日）","attribute_value_mlt":[{"subitem_date_issued_datetime":"2008-05-02","subitem_date_issued_type":"Created"}]},"item_4_date_65":{"attribute_name":"発行日","attribute_value_mlt":[{"subitem_date_issued_datetime":"1996-03-22","subitem_date_issued_type":"Created"}]},"item_4_date_80":{"attribute_name":"更新日","attribute_value_mlt":[{"subitem_date_issued_datetime":"2010-01-27","subitem_date_issued_type":"Created"}]},"item_4_description_15":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_4_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Photoelectron spectra of vanadium cluster anions, V^-_n(3≤n≤100), were measured at the photon energy of 3.49 eV by using a magnetic-bottle-type photoelectron spectrometer. A spin-polarized DV-Xα method was adopted to calculate electronic structures of V^-_4 with several possible geometric structures. These calculated spectra were compared with that obtained by the experiment to examine a geometric structure and magnetic properties of V^-_4. It is revealed that V^-_4 is spin-polarized and has ferromagnetic spin coupling. Size-dependent change in electronic affinities of V^-_4 is explained in terms of a spherical conducting droplet model.","subitem_description_type":"Abstract"}]},"item_4_description_41":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"紀要類(bulletin)","subitem_description_type":"Other"}]},"item_4_description_66":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"464052 bytes","subitem_description_type":"Other"}]},"item_4_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.50974/00043665","subitem_identifier_reg_type":"JaLC"}]},"item_4_publisher_34":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Tohoku University"}]},"item_4_radio_69":{"attribute_name":"公開範囲","attribute_value_mlt":[{"subitem_radio_item":"学外"}]},"item_4_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"00408808","subitem_source_identifier_type":"ISSN"}]},"item_4_source_id_9":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00836167","subitem_source_identifier_type":"NCID"}]},"item_4_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Iseda, M."}],"nameIdentifiers":[{"nameIdentifier":"110928","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nishio, T."}],"nameIdentifiers":[{"nameIdentifier":"110929","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Yoshida, H."}],"nameIdentifiers":[{"nameIdentifier":"110930","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Terasaki, A."}],"nameIdentifiers":[{"nameIdentifier":"110931","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kondow, T."}],"nameIdentifiers":[{"nameIdentifier":"110932","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-02-16"}],"displaytype":"detail","filename":"KJ00004200676.pdf","filesize":[{"value":"464.1 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KJ00004200676.pdf","url":"https://tohoku.repo.nii.ac.jp/record/47102/files/KJ00004200676.pdf"},"version_id":"bf8b3185-f6d2-46ee-9191-0ea465993db2"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"vanadium cluster anions","subitem_subject_scheme":"Other"},{"subitem_subject":"photoelectron spectrum","subitem_subject_scheme":"Other"},{"subitem_subject":"DV-Xα method","subitem_subject_scheme":"Other"},{"subitem_subject":"electronic structure","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Electronic Structure of Vanadium Cluster Anions : Measurement and DV-Xα Calculation of Photoelectron Spectra","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Electronic Structure of Vanadium Cluster Anions : Measurement and DV-Xα Calculation of Photoelectron Spectra"}]},"item_type_id":"4","owner":"3","path":["267"],"pubdate":{"attribute_name":"公開日","attribute_value":"2008-05-02"},"publish_date":"2008-05-02","publish_status":"0","recid":"47102","relation_version_is_last":true,"title":["Electronic Structure of Vanadium Cluster Anions : Measurement and DV-Xα Calculation of Photoelectron Spectra"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-07-27T14:59:17.936338+00:00"}