{"created":"2023-07-27T04:49:02.330593+00:00","id":50444,"links":{},"metadata":{"_buckets":{"deposit":"73307848-45ad-4a3e-8737-522a455fa09f"},"_deposit":{"created_by":3,"id":"50444","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"50444"},"status":"published"},"_oai":{"id":"oai:tohoku.repo.nii.ac.jp:00050444","sets":["72:292"]},"author_link":["123269","123268"],"item_4_alternative_title_20":{"attribute_name":"その他の言語のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"<Original Papers>Nuclear Magnetic Resonance Studies on Adduct Formation (IV) : NMR Behaviors of Amine N-Oxide Adducts and of Paramagnetic Ethyl Protons in Sulfur Ligand"}]},"item_4_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1972-11-15","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"64","bibliographicPageStart":"55","bibliographicVolumeNumber":"28","bibliographic_titles":[{"bibliographic_title":"東北大學選鑛製錬研究所彙報 = Bulletin of the Research Institute of Mineral Dressing and Metallurgy, Tohoku University"}]}]},"item_4_date_62":{"attribute_name":"登録日","attribute_value_mlt":[{"subitem_date_issued_datetime":"2008-05-02","subitem_date_issued_type":"Created"}]},"item_4_date_63":{"attribute_name":"公開日（投稿完了日）","attribute_value_mlt":[{"subitem_date_issued_datetime":"2008-05-02","subitem_date_issued_type":"Created"}]},"item_4_date_65":{"attribute_name":"発行日","attribute_value_mlt":[{"subitem_date_issued_datetime":"1972-11-15","subitem_date_issued_type":"Created"}]},"item_4_date_80":{"attribute_name":"更新日","attribute_value_mlt":[{"subitem_date_issued_datetime":"2010-01-27","subitem_date_issued_type":"Created"}]},"item_4_description_15":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_4_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Pyridine N-Oxide and its monomethyl derivatives were found to form 1 : 2 adducts with bis (diethylthiophosphato) cobalt (II) complex, Co(DMP)_2 and electron spin density distribution in these ligands was studied by NMR. The unpaired electrons of cobalt atom were observed to transfer via π bonding from cobalt (II) to oxygen atom of amine N-oxides. Existence of some steric hindrance in α-picoline N-oxide adducts was estimated from the individual behaviros of β-protons of the amine. In addition to these results, NMR spectra of sulfur ligand protons of cobalt complexes were obtained only in pyridine-CDCl_3 solutions, and from the intensity of the absorption, the resonance protons were found to be methyl protons of ethyl groups in Co(DMP)_2.","subitem_description_type":"Abstract"}]},"item_4_description_41":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"紀要類(bulletin)","subitem_description_type":"Other"}]},"item_4_description_66":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"412306 bytes","subitem_description_type":"Other"}]},"item_4_full_name_2":{"attribute_name":"著者(ヨミ)","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"123269","nameIdentifierScheme":"WEKO"}],"names":[{"name":"NANJO, Michio"}]}]},"item_4_publisher_34":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"東北大學選鉱製錬研究所"}]},"item_4_radio_69":{"attribute_name":"公開範囲","attribute_value_mlt":[{"subitem_radio_item":"学外"}]},"item_4_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0040876X","subitem_source_identifier_type":"ISSN"}]},"item_4_source_id_9":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN00168425","subitem_source_identifier_type":"NCID"}]},"item_4_version_type_16":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"南条,  道夫"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-02-20"}],"displaytype":"detail","filename":"KJ00000134958.pdf","filesize":[{"value":"412.3 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KJ00000134958.pdf","url":"https://tohoku.repo.nii.ac.jp/record/50444/files/KJ00000134958.pdf"},"version_id":"a2b78d66-8551-436c-89fa-07b918937cd6"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"<報文>付加反応のNMR法による研究(第4報) : Co(DMP)_2アミンN-オキサイド付加体および付加体中のエチルプロトンのNMR","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"<報文>付加反応のNMR法による研究(第4報) : Co(DMP)_2アミンN-オキサイド付加体および付加体中のエチルプロトンのNMR"}]},"item_type_id":"4","owner":"3","path":["292"],"pubdate":{"attribute_name":"公開日","attribute_value":"2008-05-02"},"publish_date":"2008-05-02","publish_status":"0","recid":"50444","relation_version_is_last":true,"title":["<報文>付加反応のNMR法による研究(第4報) : Co(DMP)_2アミンN-オキサイド付加体および付加体中のエチルプロトンのNMR"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-07-27T15:03:55.399102+00:00"}